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Issue 75, 2018
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Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

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Abstract

Literature casts einsteinium as a departure from earlier transplutonium actinides, with a decrease in stability constants with aminopolycarboxylate ligands. This report studies transplutonium chemistry – including Am, Bk, Cf, and Es – with aminopolycarboxylate ligands. Es complexation follows similar thermodynamic and structural trends established by the earlier actinides, consistent with first-principle calculations.

Graphical abstract: Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

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Publication details

The article was received on 02 Jul 2018, accepted on 28 Aug 2018 and first published on 29 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05230A
Citation: Chem. Commun., 2018,54, 10578-10581

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    Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

    M. P. Kelley, N. P. Bessen, J. Su, M. Urban, S. I. Sinkov, G. J. Lumetta, E. R. Batista, P. Yang and J. C. Shafer, Chem. Commun., 2018, 54, 10578
    DOI: 10.1039/C8CC05230A

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