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Issue 64, 2018
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Group 13 element containing conformationally rigid “N–E–N” heteroatomic bridged [3.3](2,6)pyridinophanes (E = B, Al)

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Abstract

The first examples of group 13 element containing pyridinophanes have been assembled using heteroatom N–E–N bridges (E = B, Al). The presence of B and Al as acceptor atoms in the bridges and their coordination with pyridine nitrogen has a very strong influence on the conformational rigidity of the pyridinophanes.

Graphical abstract: Group 13 element containing conformationally rigid “N–E–N” heteroatomic bridged [3.3](2,6)pyridinophanes (E = B, Al)

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Publication details

The article was received on 27 Jun 2018, accepted on 13 Jul 2018 and first published on 16 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC05154B
Citation: Chem. Commun., 2018,54, 8857-8860

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    Group 13 element containing conformationally rigid “N–E–N” heteroatomic bridged [3.3](2,6)pyridinophanes (E = B, Al)

    D. Bawari, C. Negi, K. Jaiswal, B. Prashanth, A. R. Choudhury and S. Singh, Chem. Commun., 2018, 54, 8857
    DOI: 10.1039/C8CC05154B

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