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Issue 74, 2018
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Pd(II), Ni(II) and Co(II)-catalyzed enantioselective additions of organoboron reagents to ketimines

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Abstract

The last two decades have witnessed the development of metal-catalyzed asymmetric additions of arylboronic acids to electron-deficient double bonds. Much research has been directed towards Rh(I)-catalysis because of the high activity of this transition metal for these types of reactions. Recently, significant advances have emerged in Pd(II), Ni(II), and Co(II)-catalyzed asymmetric additions of organoboron reagents. This feature article highlights the development of additions to ketimines catalyzed by these three metals, that is, (i) Pd(II)-catalyzed enantioselective additions of arylboronic acids to ketimines, (ii) Ni(II)-catalyzed enantioselective additions of arylboronic and alkenylboronic acids to ketimines, and (iii) Co(II)-catalyzed enantioselective additions of potassium allyltrifluoroborate to ketimines.

Graphical abstract: Pd(ii), Ni(ii) and Co(ii)-catalyzed enantioselective additions of organoboron reagents to ketimines

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Publication details

The article was received on 20 Jun 2018, accepted on 25 Jul 2018 and first published on 26 Jul 2018


Article type: Feature Article
DOI: 10.1039/C8CC04932G
Citation: Chem. Commun., 2018,54, 10394-10404

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    Pd(II), Ni(II) and Co(II)-catalyzed enantioselective additions of organoboron reagents to ketimines

    M. Quan, L. Wu, G. Yang and W. Zhang, Chem. Commun., 2018, 54, 10394
    DOI: 10.1039/C8CC04932G

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