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Issue 76, 2018
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Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism

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Abstract

Carbide clusterfullerene DyYTiC@C80-Ih with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C80 are compared to those of DySc2N@C80 and the influence of the central atom in the endohedral cluster is analyzed.

Graphical abstract: Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism

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Publication details

The article was received on 13 Jun 2018, accepted on 26 Jul 2018 and first published on 26 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC04736G
Citation: Chem. Commun., 2018,54, 10683-10686
  • Open access: Creative Commons BY license
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    Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism

    A. Brandenburg, D. S. Krylov, A. Beger, A. U. B. Wolter, B. Büchner and A. A. Popov, Chem. Commun., 2018, 54, 10683
    DOI: 10.1039/C8CC04736G

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