1,2,4-Triazolium ions as flexible scaffolds for the construction of polyphilic ionic liquid crystals

Alessio Riccobono; Rachel R. Parker; Adrian C. Whitwood; John M. Slattery; Duncan W. Bruce; Ivana Pibiri; Andrea Pace

doi:10.1039/C8CC04704A

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1,2,4-Triazolium ions as flexible scaffolds for the construction of polyphilic ionic liquid crystals†

Alessio Riccobono,

^ab Rachel R. Parker,

^b Adrian C. Whitwood,

^b John M. Slattery,

*^b Duncan W. Bruce,

^b Ivana Pibiri

*^a and Andrea Pace

Author affiliations

* Corresponding authors

^a Università degli Studi di Palermo, Dipartimento di Scienze e Tecnologie Biologiche, Chimiche e Farmaceutiche (STEBICEF), Via delle Scienze Edificio 17, Palermo, Italy
E-mail: ivana.pibiri@unipa.it

^b Department of Chemistry, University of York, Heslington, York, UK
E-mail: john.slattery@york.ac.uk

Abstract

A novel scaffold for the construction of self-organised ionic liquids and ionic liquid crystals bearing both perfluorocarbon and hydrocarbon moieties has been developed. The phase behaviour and physical properties of these materials can be tuned as a function of chain length and fluorine content and significant structural elaboration is possible, giving a highly flexible system.

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DOI: https://doi.org/10.1039/C8CC04704A
Article type: Communication
Submitted: 12 Jun 2018
Accepted: 10 Aug 2018
First published: 14 Aug 2018

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Chem. Commun., 2018,54, 9965-9968

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1,2,4-Triazolium ions as flexible scaffolds for the construction of polyphilic ionic liquid crystals

A. Riccobono, R. R. Parker, A. C. Whitwood, J. M. Slattery, D. W. Bruce, I. Pibiri and A. Pace, Chem. Commun., 2018, 54, 9965 DOI: 10.1039/C8CC04704A

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Chemical Communications

1,2,4-Triazolium ions as flexible scaffolds for the construction of polyphilic ionic liquid crystals†

Abstract

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1,2,4-Triazolium ions as flexible scaffolds for the construction of polyphilic ionic liquid crystals

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