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Issue 64, 2018
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Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds

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Abstract

A blue light-promoted cross-coupling of two distinct diazo compounds was described. The reaction produces E-configured trisubstituted alkenes in good yields in the absence of catalysts and additives. The reactive free carbene intermediates were generated via selective photolysis of one of the two diazo compounds upon blue light irradiation.

Graphical abstract: Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds

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Publication details

The article was received on 09 Jun 2018, accepted on 13 Jul 2018 and first published on 17 Jul 2018


Article type: Communication
DOI: 10.1039/C8CC04609C
Chem. Commun., 2018,54, 8865-8868

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    Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds

    T. Xiao, M. Mei, Y. He and L. Zhou, Chem. Commun., 2018, 54, 8865
    DOI: 10.1039/C8CC04609C

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