Issue 72, 2018

Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

Abstract

A new family of mononuclear lanthanide complexes, where the eight coordinate lanthanide ions adopt a very rare cubic coordination geometry is reported. The Dy analogue exhibits SMM behavior with a Ueff value 95.7 K under a 0.02 T applied dc field. Ab initio calculations support the observed magnetic behavior.

Graphical abstract: Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

Supplementary files

Article information

Article type
Communication
Submitted
08 Jun 2018
Accepted
08 Aug 2018
First published
09 Aug 2018

Chem. Commun., 2018,54, 10136-10139

Author version available

Slow magnetic dynamics in a family of mononuclear lanthanide complexes exhibiting the rare cubic coordination geometry

D. I. Alexandropoulos, K. A. Schulte, K. R. Vignesh and K. R. Dunbar, Chem. Commun., 2018, 54, 10136 DOI: 10.1039/C8CC04565H

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