Jump to main content
Jump to site search

Issue 63, 2018
Previous Article Next Article

1,2-Diarylation of alkenes with aryldiazonium salts and arenes enabled by visible light photoredox catalysis

Author affiliations

Abstract

A mild and general visible light photoredox catalysis-induced intermolecular three-component alkene 1,2-diarylation involving aryl C(sp2)–H functionalization is described. The key to controlling the chemoselectivity toward alkene 1,2-diarylation is the employment of a 2,2′-bipyridine base, thus allowing the formation of two new C(sp3)–C(sp2) bonds via aryl radical formation from aryldiazonium salts, addition across the C[double bond, length as m-dash]C bonds, and aryl C(sp2)–H functionalization cascades.

Graphical abstract: 1,2-Diarylation of alkenes with aryldiazonium salts and arenes enabled by visible light photoredox catalysis

Back to tab navigation

Supplementary files

Article information


Submitted
06 Jun 2018
Accepted
11 Jul 2018
First published
11 Jul 2018

Chem. Commun., 2018,54, 8745-8748
Article type
Communication

1,2-Diarylation of alkenes with aryldiazonium salts and arenes enabled by visible light photoredox catalysis

X. Ouyang, J. Cheng and J. Li, Chem. Commun., 2018, 54, 8745
DOI: 10.1039/C8CC04526G

Social activity

Search articles by author

Spotlight

Advertisements