Issue 42, 2018
From the journal:

Chemical Communications

Copper-catalyzed cross-coupling of aryl-, primary alkyl-, and secondary alkylboranes with heteroaryl bromides†

Allison M. Bergmann,a   Adam M. Oldham,a   Wei Youa  and  M. Kevin Brown ORCID logo *a  

* Corresponding authors

a Indiana University, Department of Chemistry, 800 E. Kirkwood Ave., Bloomington, IN 47401, USA
E-mail: brownmkb@indiana.edu

Abstract

A method for the Cu-catalyzed cross-coupling of both aryl and alkylboranes with aryl bromides is described. The method employs an inexpensive Cu-catalyst and functions for a variety of heterocyclic as well as electron deficient aryl bromides. In addition, aryl iodides of varying substitution patterns and electronic properties work well.

Graphical abstract: Copper-catalyzed cross-coupling of aryl-, primary alkyl-, and secondary alkylboranes with heteroaryl bromides

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Article information

DOI
https://doi.org/10.1039/C8CC03145B
Article type
Communication
Submitted
18 Apr 2018
Accepted
02 May 2018
First published
03 May 2018

Chem. Commun., 2018,54, 5381-5384

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Copper-catalyzed cross-coupling of aryl-, primary alkyl-, and secondary alkylboranes with heteroaryl bromides

A. M. Bergmann, A. M. Oldham, W. You and M. K. Brown, Chem. Commun., 2018, 54, 5381 DOI: 10.1039/C8CC03145B

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