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Issue 59, 2018
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Directed ortho C–H borylation catalyzed using Cp*Rh(III)–NHC complexes

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Abstract

Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(III) complexes demonstrated high selectivity in pyridine-directed ortho-C–H borylation of arenes under mild conditions.

Graphical abstract: Directed ortho C–H borylation catalyzed using Cp*Rh(iii)–NHC complexes

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Supplementary files

Publication details

The article was received on 18 Apr 2018, accepted on 28 Jun 2018 and first published on 28 Jun 2018


Article type: Communication
DOI: 10.1039/C8CC03144D
Citation: Chem. Commun., 2018,54, 8202-8205

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    Directed ortho C–H borylation catalyzed using Cp*Rh(III)–NHC complexes

    J. Thongpaen, T. E. Schmid, L. Toupet, V. Dorcet, M. Mauduit and O. Baslé, Chem. Commun., 2018, 54, 8202
    DOI: 10.1039/C8CC03144D

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