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Issue 61, 2018
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Palladium-metalated porous organic polymers as recyclable catalysts for chemoselective decarbonylation of aldehydes

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Abstract

A novel palladium nanoparticle (NP)-metalated porous organic ligand (Pd NPs/POL-xantphos) has been prepared for the chemoselective decarbonylation of aldehydes. This heterogenous catalyst not only has excellent catalytic activity and chemoselectivity, but also holds high activity after 10 runs of reuse. The effective usage of this method is demonstrated through the synthesis of biofuels such as furfuryl alcohol (FFA) via the highly chemoselective decarbonylation of biomass-derived 5-hydroxy-methylfurfural (HMF) with a TON up to 1540. More importantly, 9-fluorenone could be obtained in one step through the decarbonylation of 2-bromobenzaldehyde by using this heterogeneous catalyst.

Graphical abstract: Palladium-metalated porous organic polymers as recyclable catalysts for chemoselective decarbonylation of aldehydes

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Article information


Submitted
18 Apr 2018
Accepted
31 May 2018
First published
31 May 2018

Chem. Commun., 2018,54, 8446-8449
Article type
Communication

Palladium-metalated porous organic polymers as recyclable catalysts for chemoselective decarbonylation of aldehydes

W. Li, C. Li, Y. Li, H. Tang, H. Wang, Y. Pan and Y. Ding, Chem. Commun., 2018, 54, 8446
DOI: 10.1039/C8CC03109F

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