Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer

Myung Hyun Kim; Jaewon Choi; Kyoung Chul Ko; Kyoungil Cho; Ji Hoon Park; Sang Moon Lee; Hae Jin Kim; Yoon-Joo Ko; Jin Yong Lee; Seung Uk Son

doi:10.1039/C8CC02788A

Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer†

Myung Hyun Kim,‡^a Jaewon Choi,‡^a Kyoung Chul Ko,

^a Kyoungil Cho,^a Ji Hoon Park,^b Sang Moon Lee,^c Hae Jin Kim,^c Yoon-Joo Ko,^d Jin Yong Lee

*^a and Seung Uk Son

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea
E-mail: sson@skku.edu, jinylee@skku.edu

^b Korea Research Institute of Chemical Technology, Daejeon 34114, Korea

^c Korea Basic Science Institute, Daejeon 34133, Korea

^d Laboratory of Nuclear Magnetic Resonance, NCIRF, Seoul National University, Seoul 08826, Korea

Abstract

Hollow and microporous organic network bearing alkynone moieties was prepared via carbonylative Sonogashira coupling. The carbonyl groups in the network showed unusual chemical reactivities, compared with those of a model alkynone compound. The observed differences between the reactivities of alkynones in the molecule and in the network were analyzed based on the “network effect”.

Chemical Communications

Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Network-controlled unique reactivities of carbonyl groups in hollow and microporous organic polymer

Social activity

Search articles by author

Spotlight

Advertisements