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Issue 45, 2018
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Foldamer-based helicate displaying reversible switching between two distinct conformers

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Abstract

A new double-stranded dinuclear helicate that displays conformational switching in response to temperature was prepared by self-assembly of an aromatic helical foldamer and dichloropalladium(II). The relative populations of the two helicate conformers, synanti and synsyn, were demonstrated to be reversibly modulated through temperature control.

Graphical abstract: Foldamer-based helicate displaying reversible switching between two distinct conformers

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Article information


Submitted
06 Apr 2018
Accepted
11 May 2018
First published
21 May 2018

Chem. Commun., 2018,54, 5740-5743
Article type
Communication

Foldamer-based helicate displaying reversible switching between two distinct conformers

H. Jeon, H. K. Lee, S. Lee and K. Jeong, Chem. Commun., 2018, 54, 5740
DOI: 10.1039/C8CC02758G

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