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Issue 45, 2018
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A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

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Abstract

Homo (Au3)- and heterotrinuclear coinage metal complexes (Au2Ag and Au2Cu) ligated by the first tritopic carbanionic N-heterocyclic carbene (NHC) have been prepared by deprotonation of ditopic NHC digold complexes and structurally characterized by single-crystal X-ray diffraction.

Graphical abstract: A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

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Article information


Submitted
19 Mar 2018
Accepted
06 May 2018
First published
09 May 2018

Chem. Commun., 2018,54, 5736-5739
Article type
Communication

A tritopic carbanionic N-heterocyclic dicarbene and its homo- and heterometallic coinage metal complexes

F. Zhang, X. Cao, J. Wang, J. Jiao, Y. Huang, M. Shi, P. Braunstein and J. Zhang, Chem. Commun., 2018, 54, 5736
DOI: 10.1039/C8CC02192A

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