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Issue 40, 2018
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Argentate(i) and (iii) complexes as intermediates in silver-mediated cross-coupling reactions

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Abstract

Despite the potential of silver to mediate synthetically valuable cross-coupling reactions, the operating mechanisms have remained unknown. Here, we use a combination of rapid-injection NMR spectroscopy, electrospray-ionization mass spectrometry, and quantum chemical calculations to demonstrate that these transformations involve argentate(I) and (III) complexes as key intermediates.

Graphical abstract: Argentate(i) and (iii) complexes as intermediates in silver-mediated cross-coupling reactions

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Supplementary files

Article information


Submitted
01 Mar 2018
Accepted
16 Apr 2018
First published
30 Apr 2018

This article is Open Access

Chem. Commun., 2018,54, 5086-5089
Article type
Communication

Argentate(I) and (III) complexes as intermediates in silver-mediated cross-coupling reactions

S. Weske, R. A. Hardin, T. Auth, R. A. J. O’Hair, K. Koszinowski and C. A. Ogle, Chem. Commun., 2018, 54, 5086
DOI: 10.1039/C8CC01707G

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    [Original citation] - Published by The Royal Society of Chemistry.

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