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Issue 34, 2018
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Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes

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Abstract

In binary ionic liquid/Li salt mixtures with the novel asymmetric anion FTFSI, electrophoretic mobility μi values of all ion species were determined using electrophoretic NMR. Li was determined to migrate in negatively charged Li-anion clusters towards the anode. This vehicular transport mechanism was shown to have decreasing relevance at elevated salt concentrations.

Graphical abstract: Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes

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Article information


Submitted
19 Feb 2018
Accepted
27 Mar 2018
First published
28 Mar 2018

Chem. Commun., 2018,54, 4278-4281
Article type
Communication

Relevance of ion clusters for Li transport at elevated salt concentrations in [Pyr12O1][FTFSI] ionic liquid-based electrolytes

M. Brinkkötter, G. A. Giffin, A. Moretti, S. Jeong, S. Passerini and M. Schönhoff, Chem. Commun., 2018, 54, 4278
DOI: 10.1039/C8CC01416G

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