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Issue 41, 2018
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A [FeIII(Tp)(CN)3] scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

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Abstract

Using a scorpionate-based complex, [FeIII(Tp)(CN)3], as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

Graphical abstract: A [FeIII(Tp)(CN)3]− scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

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Publication details

The article was received on 16 Feb 2018, accepted on 15 Apr 2018 and first published on 17 Apr 2018


Article type: Communication
DOI: 10.1039/C8CC01374H
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Chem. Commun., 2018,54, 5189-5192

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    A [FeIII(Tp)(CN)3] scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

    J. Jiménez, A. Sugahara, M. Okubo, A. Yamada, L. Chamoreau, L. Lisnard and R. Lescouëzec, Chem. Commun., 2018, 54, 5189
    DOI: 10.1039/C8CC01374H

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