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Issue 53, 2018
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Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional framework

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Abstract

A rylene annulated phthalocyanine (ZnPcPDI4) was designed and synthesized. Single-crystal X-ray diffraction analyses unambiguously confirmed the giant molecule quasi-planar “four leaf clover” skeleton with a 27 Å diameter and a two-dimensional cage-like supramolecular structure. The fully conjugated characteristics endowed it with significant Q-band red-shifts to the near-infrared region of 785 nm, and a largely degenerated LUMO level.

Graphical abstract: Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional framework

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Supplementary files

Article information


Submitted
11 Feb 2018
Accepted
21 Apr 2018
First published
23 Apr 2018

Chem. Commun., 2018,54, 7294-7297
Article type
Communication

Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional framework

J. Feng, L. Fu, T. Huang, H. Geng, W. Jiang and Z. Wang, Chem. Commun., 2018, 54, 7294
DOI: 10.1039/C8CC01216D

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