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Issue 20, 2018
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Extension of antiaromatic norcorrole by cycloaddition

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Abstract

The antiaromatic ring of norcorrole, a contracted tetrapyrrolic porphyrinoid, was subjected to [2+3] dipolar cycloaddition of iminonitriles. The paratropic character of the resulting chiral chlorins was retained. The chlorins were easily dehydrogenated in the presence of air, yielding pyrazole-fused norcorroles with markedly enhanced paratropicity.

Graphical abstract: Extension of antiaromatic norcorrole by cycloaddition

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Article information


Submitted
18 Jan 2018
Accepted
13 Feb 2018
First published
13 Feb 2018

Chem. Commun., 2018,54, 2510-2513
Article type
Communication

Extension of antiaromatic norcorrole by cycloaddition

X. Fu, Y. Meng, X. Li, M. Stępień and P. J. Chmielewski, Chem. Commun., 2018, 54, 2510
DOI: 10.1039/C8CC00447A

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