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Issue 14, 2018

Dearylation of arylphosphine oxides using a sodium hydride–iodide composite

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Abstract

A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion.

Graphical abstract: Dearylation of arylphosphine oxides using a sodium hydride–iodide composite

Supplementary files

Article information


Submitted
12 Jan 2018
Accepted
24 Jan 2018
First published
24 Jan 2018

Chem. Commun., 2018,54, 1782-1785
Article type
Communication

Dearylation of arylphosphine oxides using a sodium hydride–iodide composite

C. Tejo, J. H. Pang, D. Y. Ong, M. Oi, M. Uchiyama, R. Takita and S. Chiba, Chem. Commun., 2018, 54, 1782 DOI: 10.1039/C8CC00289D

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