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Issue 15, 2018
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Imido-P(V) trianion supported enantiopure neutral tetrahedral Pd(II) cages

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Abstract

Charge-neutral chiral hosts are attractive due to their ability to recognize a wide range of guest functionalities and support enantioselective processes. However, reports on such charge-neutral cages are very scarce in the literature. Here, we report an enantiomeric pair of tetrahedral Pd(II) cages built from chiral tris(imido)phosphate trianions and oxalate linkers, which exhibit enantioselective separation capabilities for epichlorohydrin, β-butyrolactone, and 3-methyl- and 3-ethyl cyclopentanone.

Graphical abstract: Imido-P(v) trianion supported enantiopure neutral tetrahedral Pd(ii) cages

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Publication details

The article was received on 10 Jan 2018, accepted on 24 Jan 2018 and first published on 24 Jan 2018


Article type: Communication
DOI: 10.1039/C8CC00207J
Citation: Chem. Commun., 2018,54, 1873-1876

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    Imido-P(V) trianion supported enantiopure neutral tetrahedral Pd(II) cages

    P. Rajasekar, S. Pandey, H. Paithankar, J. Chugh, A. Steiner and R. Boomishankar, Chem. Commun., 2018, 54, 1873
    DOI: 10.1039/C8CC00207J

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