Issue 14, 2018

Nickel-catalyzed cross-coupling of aldehydes with aryl halides via hydrazone intermediates

Abstract

Traditional cross-couplings require stoichiometric organometallic reagents. A novel nickel-catalyzed cross-coupling reaction between aldehydes and aryl halides via hydrazone intermediates has been developed, merging the Wolff–Kishner reduction and the classical cross-coupling reactions. Aromatic aldehydes, aryl iodides and aryl bromides are especially effective in this new cross-coupling chemistry.

Graphical abstract: Nickel-catalyzed cross-coupling of aldehydes with aryl halides via hydrazone intermediates

Supplementary files

Article information

Article type
Communication
Submitted
05 Dec 2017
Accepted
22 Jan 2018
First published
22 Jan 2018

Chem. Commun., 2018,54, 1750-1753

Nickel-catalyzed cross-coupling of aldehydes with aryl halides via hydrazone intermediates

J. Tang, L. Lv, X. Dai, C. Li, L. Li and C. Li, Chem. Commun., 2018, 54, 1750 DOI: 10.1039/C7CC09290C

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