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Issue 8, 2018

Indications of magnetic coupling effects in spin cross-over molecular thin films

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Abstract

Room temperature isothermal reversible spin crossover switching of [Fe(H2B(pz)2)2(bipy)] thin films is demonstrated. The magnetic oxide substrate locks the [Fe{H2B(pz)2}2(bipy)] largely in a low spin state. With an X-ray fluence, excitation to a high spin state occurs, while relaxation back to low spin state is aided by alternating the substrate magnetization.

Graphical abstract: Indications of magnetic coupling effects in spin cross-over molecular thin films

Supplementary files

Article information


Submitted
25 Oct 2017
Accepted
27 Dec 2017
First published
02 Jan 2018

Chem. Commun., 2018,54, 944-947
Article type
Communication

Indications of magnetic coupling effects in spin cross-over molecular thin films

X. Zhang, A. T. N'Diaye, X. Jiang, X. Zhang, Y. Yin, X. Chen, X. Hong, X. Xu and P. A. Dowben, Chem. Commun., 2018, 54, 944 DOI: 10.1039/C7CC08246K

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