Efficient visible light-driven water oxidation catalysts based on B-β-{BiW8O30} and unique 14-nuclear hetero-metal sandwich unit

Lige Gong; Li Yu; Kai Yu; Yong Ding; Jinhua Lv; Chunmei Wang; Zhanhua Su; Baibin Zhou

doi:10.1039/C7CC06064E

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Efficient visible light-driven water oxidation catalysts based on B-β-{BiW₈O₃₀} and unique 14-nuclear hetero-metal sandwich unit†

Lige Gong,^a Li Yu,^b Kai Yu,

*^a Yong Ding,

*^b Jinhua Lv,^a Chunmei Wang,^a Zhanhua Su

^a and Baibin Zhou

*^a

Author affiliations

* Corresponding authors

^a Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, Harbin Normal University, Harbin 150025, People's Republic of China
E-mail: hlyukai188@163.com, zhou_bai_bin@163.com

^b State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University, Lanzhou 730000, People's Republic of China
E-mail: dingyong1@lzu.edu.cn

Abstract

A sandwich tungstobismuthate with new topology based on {B-β-BiW₈O₃₀}-cluster and unique 14-nuclear sandwich unit is reported as a high-efficiency visible light-driven water oxidation catalyst containing extended hetero-metal oxygen layer. At optimal conditions, the turn-over number (TON) of the title compound can reach 205.5 with O₂ yield of 32.88%.

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Article information

DOI: https://doi.org/10.1039/C7CC06064E
Article type: Communication
Submitted: 03 Aug 2017
Accepted: 20 Dec 2017
First published: 20 Dec 2017

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Chem. Commun., 2018,54, 674-677

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Efficient visible light-driven water oxidation catalysts based on B-β-{BiW₈O₃₀} and unique 14-nuclear hetero-metal sandwich unit

L. Gong, L. Yu, K. Yu, Y. Ding, J. Lv, C. Wang, Z. Su and B. Zhou, Chem. Commun., 2018, 54, 674 DOI: 10.1039/C7CC06064E

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Chemical Communications