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Issue 90, 2017
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Highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by Ru(ii)Pheox complexes

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Abstract

A highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by chiral Ru(II)–Pheox complexes was developed to give chiral cyclopropyl sulfones in high yields (up to 99%) with excellent trans-selectivity and enantioselectivity (up to 98% ee).

Graphical abstract: Highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by Ru(ii)–Pheox complexes

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Article information


Submitted
31 Jul 2017
Accepted
18 Oct 2017
First published
18 Oct 2017

Chem. Commun., 2017,53, 12193-12196
Article type
Communication

Highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by Ru(II)Pheox complexes

M. Kotozaki, S. Chanthamath, I. Fujisawa, K. Shibatomi and S. Iwasa, Chem. Commun., 2017, 53, 12193
DOI: 10.1039/C7CC05951E

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