Issue 74, 2017
From the journal:

Chemical Communications

Graphene oxide as a catalyst for the diastereoselective transfer hydrogenation in the synthesis of prostaglandin derivatives†

Simona M. Coman,a   Iunia Podolean,a   Madalina Tudorache,a   Bogdan Cojocaru,a   Vasile I. Parvulescu, ORCID logo *a   Marta Pucheb  and  Hermenegildo Garcia ORCID logo *b  

* Corresponding authors

a Department of Organic Chemistry, Biochemistry and Catalysis, Chemistry, University of Bucharest, Bdul Regina Elisabeta 4-12, Bucharest 030016, Romania
E-mail: vasile.parvulescu@chimie.unibuc.ro

b Instituto Universitario de Tecnología Química CSIC-UPV, Universitat Politecnica de Valencia, Av. de los Naranjos s/n, 46022 Valencia, Spain
E-mail: hgarcia@qim.upv.es

Abstract

Modification of GO by organic molecules changes its catalytic activity in the hydrogen transfer from i-propanol to enones, affecting the selectivity to allyl alcohol and diastereoselectivity to the resulting stereoisomers. It is noteworthy the system does not contain metals and is recyclable.

Graphical abstract: Graphene oxide as a catalyst for the diastereoselective transfer hydrogenation in the synthesis of prostaglandin derivatives

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Article information

DOI
https://doi.org/10.1039/C7CC05105K
Article type
Communication
Submitted
02 Jul 2017
Accepted
16 Aug 2017
First published
01 Sep 2017

Chem. Commun., 2017,53, 10271-10274

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Graphene oxide as a catalyst for the diastereoselective transfer hydrogenation in the synthesis of prostaglandin derivatives

S. M. Coman, I. Podolean, M. Tudorache, B. Cojocaru, V. I. Parvulescu, M. Puche and H. Garcia, Chem. Commun., 2017, 53, 10271 DOI: 10.1039/C7CC05105K

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