Issue 65, 2017

Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst

Abstract

Visible light-mediated α-arylation of α,β-unsaturated imides is achieved via aminium radicals generated from diarylalkylamines using a photoredox catalyst. On the basis of emission quenching experiments, a plausible pathway of the reaction is discussed.

Graphical abstract: Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst

Supplementary files

Article information

Article type
Communication
Submitted
20 Jun 2017
Accepted
26 Jul 2017
First published
26 Jul 2017

Chem. Commun., 2017,53, 9136-9138

Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst

Y. Ando, T. Kamatsuka, H. Shinokubo and Y. Miyake, Chem. Commun., 2017, 53, 9136 DOI: 10.1039/C7CC04776B

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