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Issue 63, 2017
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New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex

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Abstract

A (μ-peroxo)diiron(III) complex [Fe2(LPh4)(O2)(Ph3CCO2)]2+ (1-O2) with a dinucleating ligand (LPh4), generated from the reaction of a carboxylate bridged diiron(II) complex [Fe2(LPh4)(Ph3CCO2)]2+ (1) with dioxygen in CH2Cl2, provides a diiron(IV)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.

Graphical abstract: New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(iii) complex

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Supplementary files

Article information


Submitted
06 Jun 2017
Accepted
13 Jul 2017
First published
13 Jul 2017

Chem. Commun., 2017,53, 8838-8841
Article type
Communication

New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(III) complex

M. Sekino, H. Furutachi, R. Tojo, A. Hishi, H. Kajikawa, T. Suzuki, K. Suzuki, S. Fujinami, S. Akine, Y. Sakata, T. Ohta, S. Hayami and M. Suzuki, Chem. Commun., 2017, 53, 8838 DOI: 10.1039/C7CC04382A

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