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Issue 60, 2017
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A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons

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Abstract

A solvent-dependent oxidative dearomatization-induced divergent [5+2] cascade approach to bicyclo[3.2.1]octanes was described. This novel protocol enables a facile synthesis of a series of diversely functionalized ent-kaurene and cedrene-type skeletons in good yields and excellent diastereoselectivities.

Graphical abstract: A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons

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Article information


Submitted
03 Jun 2017
Accepted
05 Jul 2017
First published
05 Jul 2017

Chem. Commun., 2017,53, 8435-8438
Article type
Communication

A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons

C. He, Z. Bai, J. Hu, B. Wang, H. Xie, L. Yu and H. Ding, Chem. Commun., 2017, 53, 8435
DOI: 10.1039/C7CC04292B

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