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Issue 48, 2017
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A chimeric design of heterospin 2p–3d, 2p–4f, and 2p–3d–4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

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Abstract

End-off bicompartmental ligands bearing a nitronyl–nitroxide arm have been designed for synthesizing various heterospin molecular systems. These ligands can selectively interact with 3d and 4f metal ions, leading to 2p–4f, 2p–3d, and 2p–3d–4f complexes. The magnetic properties of the 2p–4f and 2p–3d–4f complexes have been investigated and rationalized by theoretical calculations.

Graphical abstract: A chimeric design of heterospin 2p–3d, 2p–4f, and 2p–3d–4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

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Article information


Submitted
27 Apr 2017
Accepted
23 May 2017
First published
23 May 2017

Chem. Commun., 2017,53, 6504-6507
Article type
Communication

A chimeric design of heterospin 2p–3d, 2p–4f, and 2p–3d–4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

A. A. Patrascu, S. Calancea, M. Briganti, S. Soriano, A. M. Madalan, R. A. A. Cassaro, A. Caneschi, F. Totti, M. G. F. Vaz and M. Andruh, Chem. Commun., 2017, 53, 6504
DOI: 10.1039/C7CC03236F

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