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Issue 42, 2017

An example of unusual pyridine donor Schiff base uranyl (UO22+) complexes

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Abstract

The pentadentate coordination environment of a 2,6-bis[1-[(2-hydroxyphenyl)imino]ethyl] pyridine ligand scaffold was designed to accommodate the larger atomic radius of uranium as the uranyl dioxo cation, while fully occupying its equatorial plane. Here, two new uranyl (UO22+) complexes utilizing this scaffold have been synthesized from successive condensation reactions and subsequent metal complexation. Surprising Zn fluorescence is also discussed.

Graphical abstract: An example of unusual pyridine donor Schiff base uranyl (UO22+) complexes

Supplementary files

Article information


Submitted
10 Apr 2017
Accepted
02 May 2017
First published
03 May 2017

Chem. Commun., 2017,53, 5718-5720
Article type
Communication

An example of unusual pyridine donor Schiff base uranyl (UO22+) complexes

E. E. Hardy, K. M. Wyss, M. A. Eddy and A. E. V. Gorden, Chem. Commun., 2017, 53, 5718 DOI: 10.1039/C7CC02747H

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