Formation of (PNP)Rh complexes containing covalent rhodium–zinc bonds in studies of potential Rh-catalysed Negishi coupling

Christopher J. Pell; Wei-Chun Shih; Sylvain Gatard; Oleg V. Ozerov

doi:10.1039/C7CC02707A

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Formation of (PNP)Rh complexes containing covalent rhodium–zinc bonds in studies of potential Rh-catalysed Negishi coupling†

Christopher J. Pell,^a Wei-Chun Shih,^a Sylvain Gatard

‡^b and Oleg V. Ozerov

*^a

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* Corresponding authors

^a Department of Chemistry, Texas A&M University, College Station, TX 77842, USA
E-mail: ozerov@chem.tamu.edu

^b Department of Chemistry, Brandeis University, 415 South Street, Waltham, MA 02453, USA

Abstract

While investigating rhodium-catalyzed Negishi coupling, it was observed that the (PNP)Rh fragment readily inserted into zinc–carbon bonds to form isolable molecules with covalent rhodium–zinc bonds.

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DOI: https://doi.org/10.1039/C7CC02707A
Article type: Communication
Submitted: 07 Apr 2017
Accepted: 22 May 2017
First published: 23 May 2017

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Chem. Commun., 2017,53, 6456-6459

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Formation of (PNP)Rh complexes containing covalent rhodium–zinc bonds in studies of potential Rh-catalysed Negishi coupling

C. J. Pell, W. Shih, S. Gatard and O. V. Ozerov, Chem. Commun., 2017, 53, 6456 DOI: 10.1039/C7CC02707A

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Chemical Communications

Formation of (PNP)Rh complexes containing covalent rhodium–zinc bonds in studies of potential Rh-catalysed Negishi coupling†

Abstract

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Formation of (PNP)Rh complexes containing covalent rhodium–zinc bonds in studies of potential Rh-catalysed Negishi coupling

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