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Issue 51, 2017
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A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure

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Abstract

Supramolecular assembly of an engineered hemoprotein with an externally-attached heme moiety via an azobenzene or stilbene linker demonstrates drastic structural transitions between two distinct forms: the thermodynamically stable fiber-type assembly and the kinetically trapped metastable micelle-type assembly induced by transient thermal stimulus.

Graphical abstract: A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure

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Article information


Submitted
06 Apr 2017
Accepted
02 Jun 2017
First published
06 Jun 2017

Chem. Commun., 2017,53, 6879-6882
Article type
Communication

A supramolecular assembly based on an engineered hemoprotein exhibiting a thermal stimulus-driven conversion to a new distinct supramolecular structure

K. Oohora, Y. Onuma, Y. Tanaka, A. Onoda and T. Hayashi, Chem. Commun., 2017, 53, 6879
DOI: 10.1039/C7CC02678A

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