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Issue 48, 2017
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Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework

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Abstract

Metal Organic Frameworks (MOFs) have been recently proposed as promising electrocatalysts, yet the exact nature of the mechanisms in play has not been addressed in depth. By comparing the electrocatalytic activity of a MOF for the oxygen reduction reaction (ORR) and the corresponding molecular building units through electrochemical techniques, here, we investigate the nature of the catalytic sites, their redox states and the electron transfer pathways.

Graphical abstract: Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework

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Article information


Submitted
20 Mar 2017
Accepted
23 May 2017
First published
23 May 2017

Chem. Commun., 2017,53, 6496-6499
Article type
Communication

Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework

M. Lions, J.-B. Tommasino, R. Chattot, B. Abeykoon, N. Guillou, T. Devic, A. Demessence, L. Cardenas, F. Maillard and A. Fateeva, Chem. Commun., 2017, 53, 6496
DOI: 10.1039/C7CC02113E

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