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Issue 48, 2017
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Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework

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Abstract

Metal Organic Frameworks (MOFs) have been recently proposed as promising electrocatalysts, yet the exact nature of the mechanisms in play has not been addressed in depth. By comparing the electrocatalytic activity of a MOF for the oxygen reduction reaction (ORR) and the corresponding molecular building units through electrochemical techniques, here, we investigate the nature of the catalytic sites, their redox states and the electron transfer pathways.

Graphical abstract: Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework

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Publication details

The article was received on 20 Mar 2017, accepted on 23 May 2017 and first published on 23 May 2017


Article type: Communication
DOI: 10.1039/C7CC02113E
Chem. Commun., 2017,53, 6496-6499

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    Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework

    M. Lions, J.-B. Tommasino, R. Chattot, B. Abeykoon, N. Guillou, T. Devic, A. Demessence, L. Cardenas, F. Maillard and A. Fateeva, Chem. Commun., 2017, 53, 6496
    DOI: 10.1039/C7CC02113E

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