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Issue 36, 2017
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Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

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Abstract

A method for the conjunctive functionalization of vinyl boronate complexes with electrophiles is described. The overall process represents a three-component coupling between a vinyl boronic ester, carbon nucleophile and an electrophile, thus affording complex multifunctionalized products from simple starting materials. The diastereoselectivity (syn or anti) of this process is strongly dependent upon the nature of the electrophile.

Graphical abstract: Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

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Article information


Submitted
03 Mar 2017
Accepted
07 Apr 2017
First published
20 Apr 2017

This article is Open Access

Chem. Commun., 2017,53, 4922-4925
Article type
Communication

Conjunctive functionalization of vinyl boronate complexes with electrophiles: a diastereoselective three-component coupling

R. J. Armstrong, C. Sandford, C. García-Ruiz and V. K. Aggarwal, Chem. Commun., 2017, 53, 4922 DOI: 10.1039/C7CC01671A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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