Issue 31, 2017
From the journal:

Chemical Communications

A self-contained photoacid generator for super acid based on photochromic terarylene†

Ruiji Li,a   Takuya Nakashima ORCID logo *a  and  Tsuyoshi Kawai ORCID logo *ab  

* Corresponding authors

a Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma, Nara 630-0192, Japan
E-mail: ntaku@ms.naist.jp, tkawai@ms.naist.jp

b NAIST-CEMES International Collaborative Laboratory, CEMES-CNRS (UPR 8011), Toulouse 31055, France

Abstract

A self-contained photoacid generator for super acid along with the photoinduced 6π-electrocyclization reaction of the terarylene backbone is demonstrated. The photoinitiated cationic polymerization of epoxy-monomers is achieved with an efficient photochemical quantum yield, Φacid = 0.47.

Graphical abstract: A self-contained photoacid generator for super acid based on photochromic terarylene

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC01635B
Article type
Communication
Submitted
02 Mar 2017
Accepted
24 Mar 2017
First published
24 Mar 2017

Chem. Commun., 2017,53, 4339-4341

Permissions

Request permissions

A self-contained photoacid generator for super acid based on photochromic terarylene

R. Li, T. Nakashima and T. Kawai, Chem. Commun., 2017, 53, 4339 DOI: 10.1039/C7CC01635B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements