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Issue 32, 2017
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One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation

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Abstract

A Rh/Ni-catalyzed cascade sequence of allylamine isomerization and hydrophosphonylation to synthesize α-aminophosphonates has been disclosed. The reaction, which not only allows the generation of widespread valuable α-aminophosphonates under simple systems and mild conditions, but also enriches the process of olefin isomerization–addition both in catalytic systems and various reaction types.

Graphical abstract: One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation

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Publication details

The article was received on 22 Feb 2017, accepted on 27 Mar 2017 and first published on 28 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01391D
Chem. Commun., 2017,53, 4473-4476

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    One-pot synthesis of α-aminophosphonates via a cascade sequence of allylamine isomerization/hydrophosphonylation

    L. Mao, C. Li, Q. Yang, M. Cheng and S. Yang, Chem. Commun., 2017, 53, 4473
    DOI: 10.1039/C7CC01391D

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