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Issue 37, 2017
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Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks

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Abstract

We synthesized for the first time octaphyrins with a dithieno[3,4-b:3′,4′-d]thiophene core as thiophene-fused dithiaoctaphyrins with a cross-conjugated structure. The octaphyrins revealed cross-conjugated and macrocyclic 36π-electron networks.

Graphical abstract: Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks

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Article information


Submitted
17 Feb 2017
Accepted
08 Mar 2017
First published
17 Mar 2017

Chem. Commun., 2017,53, 5091-5094
Article type
Communication

Thiophene-fused dithiaoctaphyrins: π-system switching between cross-conjugated and macrocyclic π-networks

T. Higashino, A. Kumagai and H. Imahori, Chem. Commun., 2017, 53, 5091
DOI: 10.1039/C7CC01273J

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