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Issue 32, 2017
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Construction of a bicontinuous donor–acceptor hybrid material at the molecular level by inserting inorganic nanowires into porous MOFs

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Abstract

Herein, we report an unprecedented hybrid structure of electron-rich iodoplumbate nanowires precisely inserted into the periodic pores of electron-deficient pyridinium metal–organic frameworks (MOFs). To the best of our knowledge, this is the first example of semiconductive MOFs in situ loaded with inorganic semiconductive nanowires via a simple self-assembly method. Due to the dissimilar semiconductivities between the host and guest components, this hybrid also represents the first bicontinuous donor–acceptor hybrid at the molecular level based on host–guest interactions.

Graphical abstract: Construction of a bicontinuous donor–acceptor hybrid material at the molecular level by inserting inorganic nanowires into porous MOFs

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Publication details

The article was received on 19 Jan 2017, accepted on 28 Mar 2017 and first published on 06 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC00495H
Chem. Commun., 2017,53, 4481-4484

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    Construction of a bicontinuous donor–acceptor hybrid material at the molecular level by inserting inorganic nanowires into porous MOFs

    J. Liu, Y. Guan, L. Li, Y. Chen, W. Dai, C. Huang and M. Lin, Chem. Commun., 2017, 53, 4481
    DOI: 10.1039/C7CC00495H

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