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Issue 28, 2017
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Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines

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Abstract

A ligand controlled catalytic system for the aerobic oxidation of 1° amines to nitriles and imines has been developed where the varying π-acidic feature of BIAN versus phen in the frameworks of ruthenium catalysts facilitates switchable selectivity.

Graphical abstract: Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines

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Article information


Submitted
23 Dec 2016
Accepted
17 Mar 2017
First published
17 Mar 2017

Chem. Commun., 2017,53, 4006-4009
Article type
Communication

Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines

R. Ray, S. Chandra, V. Yadav, P. Mondal, D. Maiti and G. K. Lahiri, Chem. Commun., 2017, 53, 4006
DOI: 10.1039/C6CC10200J

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