Issue 16, 2017

Wheel-to-rhomboid isomerization as well as nitrene transfer catalysis of ruthenium-thiolate wheels

Abstract

A unique ruthenium-thiolate molecular rhomboid (◇)-[Ru(SAr)2(CO)2]8, which consists of eight octahedra linked by alternate face- and vertex-sharing, was produced by isomerization of the molecular wheel (○)-[Ru(SAr)2(CO)2]8 at elevated temperature. The use of a (○)-[Ru(SAr)2(CO)2]6 wheel for catalytic aziridination of alkenes via nitrene transfer is also described.

Graphical abstract: Wheel-to-rhomboid isomerization as well as nitrene transfer catalysis of ruthenium-thiolate wheels

Supplementary files

Article information

Article type
Communication
Submitted
13 Dec 2016
Accepted
17 Jan 2017
First published
25 Jan 2017

Chem. Commun., 2017,53, 2419-2422

Wheel-to-rhomboid isomerization as well as nitrene transfer catalysis of ruthenium-thiolate wheels

K. C. Tso, S. L. Chan, J. Huang and C. Che, Chem. Commun., 2017, 53, 2419 DOI: 10.1039/C6CC09903C

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