Issue 6, 2017

Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects

Abstract

Dissymmetrical substitution of norcorrole enables the preparation of various norcorrole derivatives as air- and moisture-stable species. Intramolecular charge transfer interactions between electron-donating substituents and the norcorrole core in these norcorroles significantly enhanced their low-energy absorption bands, which were forbidden in symmetrical NiII dimesitylnorcorrole.

Graphical abstract: Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects

Supplementary files

Article information

Article type
Communication
Submitted
26 Nov 2016
Accepted
20 Dec 2016
First published
21 Dec 2016

Chem. Commun., 2017,53, 1112-1115

Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects

T. Yoshida, D. Sakamaki, S. Seki and H. Shinokubo, Chem. Commun., 2017, 53, 1112 DOI: 10.1039/C6CC09444A

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