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Issue 2, 2017
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Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

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Abstract

The synthesis of a wide variety of carbamates from amines, alcohols and carbon monoxide has been achieved by means of a Rh-catalysed oxidative carbonylation reaction that uses Oxone as a stoichiometric oxidant. In-depth studies on the reaction mechanism shed light on the intimate role of Oxone in the catalytic cycle.

Graphical abstract: Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

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Article information


Submitted
15 Nov 2016
Accepted
06 Dec 2016
First published
06 Dec 2016

Chem. Commun., 2017,53, 404-407
Article type
Communication

Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

A. Iturmendi, M. Iglesias, J. Munárriz, V. Polo, J. J. Pérez-Torrente and L. A. Oro, Chem. Commun., 2017, 53, 404
DOI: 10.1039/C6CC09133D

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