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Issue 6, 2017
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Allyl borates: a novel class of polyhomologation initiators

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Abstract

Allyl borates, a new class of monofunctional polyhomologation initiators, are reported. These monofunctional initiators are less sensitive and more effective towards polymethylene-based architectures. As an example, the synthesis of α-vinyl-ω-hydroxypolymethylenes is given. By designing/synthesizing different allylic borate initiators, and using 1H and 11B NMR spectroscopy, the initiation mechanism was elucidated.

Graphical abstract: Allyl borates: a novel class of polyhomologation initiators

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Article information


Submitted
14 Nov 2016
Accepted
22 Dec 2016
First published
22 Dec 2016

Chem. Commun., 2017,53, 1196-1199
Article type
Communication

Allyl borates: a novel class of polyhomologation initiators

D. Wang and N. Hadjichristidis, Chem. Commun., 2017, 53, 1196
DOI: 10.1039/C6CC09047H

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