Issue 4, 2017
From the journal:

Chemical Communications

Sumanene derivatives functionalized at the internal carbon†

Niti Ngamsomprasert,a   Jing-Shuang Dang,a   Shuhei Higashibayashi,b   Yumi Yakiyamaa  and  Hidehiro Sakurai*a  

* Corresponding authors

a Division of Applied Chemistry Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: hsakurai@chem.eng.osaka-u.ac.jp

b Research Center of Integrative Molecular Systems, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan

Abstract

The first sumanene derivatives functionalized at the convex face of the internal carbon were reported. The structure of racemic hydroxysumanenone was confirmed by X-ray crystal analysis. The obtained structure was composed of the single enantiomer.

Graphical abstract: Sumanene derivatives functionalized at the internal carbon

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Article information

DOI
https://doi.org/10.1039/C6CC08970D
Article type
Communication
Submitted
10 Nov 2016
Accepted
25 Nov 2016
First published
25 Nov 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2017,53, 697-700

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Sumanene derivatives functionalized at the internal carbon

N. Ngamsomprasert, J. Dang, S. Higashibayashi, Y. Yakiyama and H. Sakurai, Chem. Commun., 2017, 53, 697 DOI: 10.1039/C6CC08970D

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