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Issue 79, 2016
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Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site

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Abstract

The palladium diphosphinoboryl pincer [{(o-PPh2C6H4)2B}PdIII] 8 was prepared from the diphosphinoborane complex 6a. The boryl functionality of the pincer displayed ambiphilic properties allowing: (1) coordination of Lewis basic pyridines to the boryl site and (2) access to palladium diphosphinoborane complex derivatives.

Graphical abstract: Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site

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Article information


Submitted
29 Aug 2016
Accepted
05 Sep 2016
First published
06 Sep 2016

Chem. Commun., 2016,52, 11823-11826
Article type
Communication

Isolation and properties of a palladium PBP pincer complex featuring an ambiphilic boryl site

D. Schuhknecht, F. Ritter and M. E. Tauchert, Chem. Commun., 2016, 52, 11823
DOI: 10.1039/C6CC07079E

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