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Issue 84, 2016
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Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb)

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Abstract

Control of the structural type in metallic enantiopure and racemic radical cation salts is achieved through hydrogen bonding interactions between the chiral donor DM-EDT-TTF and the XF6 anions (X = P, As, Sb), determined by the anion size and the chiral information.

Graphical abstract: Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb)

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Publication details

The article was received on 15 Aug 2016, accepted on 27 Sep 2016 and first published on 27 Sep 2016


Article type: Communication
DOI: 10.1039/C6CC06706A
Citation: Chem. Commun., 2016,52, 12438-12441
  • Open access: Creative Commons BY license
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    Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb)

    F. Pop, P. Auban-Senzier, E. Canadell and N. Avarvari, Chem. Commun., 2016, 52, 12438
    DOI: 10.1039/C6CC06706A

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