Issue 89, 2016
From the journal:

Chemical Communications

Cu(ii)/Cu(0)@UiO-66-NH2: base metal@MOFs as heterogeneous catalysts for olefin oxidation and reduction†

Jian-Cheng Wang,a   Yu-Hong Hu,a   Gong-Jun Chena  and  Yu-Bin Dong*a  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China
E-mail: yubindong@sdnu.edu.cn

Abstract

Two copper-loaded MOF materials, namely Cu(II)@Ui-O-66-NH2 (1) and Cu(0)@UiO-66-NH2 (2), are reported. They can, respectively, serve as highly efficient heterogeneous catalysts for olefin oxidation and hydrogenation under mild conditions. Complete styrene hydrogenation occurs in 15 min at ambient temperature with quantitative yield.

Graphical abstract: Cu(ii)/Cu(0)@UiO-66-NH2: base metal@MOFs as heterogeneous catalysts for olefin oxidation and reduction

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Article information

DOI
https://doi.org/10.1039/C6CC06076E
Article type
Communication
Submitted
22 Jul 2016
Accepted
11 Oct 2016
First published
11 Oct 2016

Chem. Commun., 2016,52, 13116-13119

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Cu(II)/Cu(0)@UiO-66-NH2: base metal@MOFs as heterogeneous catalysts for olefin oxidation and reduction

J. Wang, Y. Hu, G. Chen and Y. Dong, Chem. Commun., 2016, 52, 13116 DOI: 10.1039/C6CC06076E

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