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Issue 72, 2016
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Reversible and irreversible emergence of chiroptical signals in J-aggregates of achiral 4-sulfonatophenyl substituted porphyrins: intrinsic chirality vs. chiral ordering in the solution

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Abstract

Mueller matrix polarimetry distinguishes the different origins of the reversible and irreversible chiroptical effects emerging in stirred solutions of J-aggregate nanoparticles: the reversible effect is due to an anisotropic ordering in the solution and the irreversible one is due to a bias from the racemic composition of intrinsically chiral structures.

Graphical abstract: Reversible and irreversible emergence of chiroptical signals in J-aggregates of achiral 4-sulfonatophenyl substituted porphyrins: intrinsic chirality vs. chiral ordering in the solution

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Article information


Submitted
11 Jul 2016
Accepted
10 Aug 2016
First published
10 Aug 2016

Chem. Commun., 2016,52, 10874-10877
Article type
Communication

Reversible and irreversible emergence of chiroptical signals in J-aggregates of achiral 4-sulfonatophenyl substituted porphyrins: intrinsic chirality vs. chiral ordering in the solution

O. Arteaga, Z. El-Hachemi, A. Canillas, J. Crusats, M. Rovira and J. M. Ribó, Chem. Commun., 2016, 52, 10874
DOI: 10.1039/C6CC05709H

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