Issue 59, 2016

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Abstract

The first helicene–NHC–iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting the helical and iridium-centered chirality.

Graphical abstract: Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Supplementary files

Article information

Article type
Communication
Submitted
20 May 2016
Accepted
21 Jun 2016
First published
22 Jun 2016

Chem. Commun., 2016,52, 9243-9246

Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

N. Hellou, C. Jahier-Diallo, O. Baslé, M. Srebro-Hooper, L. Toupet, T. Roisnel, E. Caytan, C. Roussel, N. Vanthuyne, J. Autschbach, M. Mauduit and J. Crassous, Chem. Commun., 2016, 52, 9243 DOI: 10.1039/C6CC04257K

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